What is really the rarest Lego color?

Chrome black.

This is a color that appear in a single set, the Chrome Darth Vader, a promotional polybag released in 2009 with a limit of 10,000. This single minifig seems to be going to about $130 on the secondary market (bricklink).

Chrome black Darth Vader helmet (left) vs black Darth Vader helmet

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